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Research Progress in High-Performance Oil-Absorbing Materials

Editor: | Dec 29,2022

 The frequent occurrence of oil spills in industry and pour of oily wastewater in daily life not only causes huge economic loss and energy consumption, but also endangers the balance of ecosystem, and even seriously threatens the health of human beings. Therefore, developing novel materials for effectively dealing with oil/water mixture is urgently necessary. Porous materials with the advantages of low density, large surface areas, and excellent oil absorption capacity has been widely applied for the oily wastewater treatment. A number of techniques, such as high-temperature heat treatment and surface fluorination, were often employed to prepared oil-absorbing materials.  However, the shortcomings of these methods are high cost and complicated process of manufacturing.

Recently, separation materials and technology research group of Xinjiang Technical Institute of Physics and Chemistry developed a simple and efficient method to fabricate scalable foam by coating siloxane on the commercial melamine foam. The process was based on the siloxane coating originated from the silanization of methyltrimethoxysilane and tetraethoxysilane, which could be easily scaled up by employing low-cost chemicals and devices (Fig. 1). The properties of the material showed that the wettability of melamine foam was changed to superhydrophobic with a water contact angle of 156° due to the presence of alkylsilane. The modified foam exhibited excellent oil/water selectivity and high oil absorption capacities of 77–163 times its own weight. The retention of absorption capacity was greater than 97% after 5000 cycles compression. These fascinating characteristics made the modified foam exceptional recyclability for commonly organic solvents and oils without obvious dissolution/swelling. Moreover, the prepared material was integrated with an apparatus to develop a prototype oil collector for the remediation of oil spills in a larger open-air environment. The devices could be readily used in a range of real-world applications, including industrial oil spill clean-up.

The research results were published in the Science of the Total Environment. The research work is supported by the project of the West Light Foundation of CAS and Tianshan Qingnian Program of Xinjiang.

Fig. 1 Preparation, properties, and application of high-performance oil-absorbing material

 

Article:

Mu L, Yue X, Hao B, Wang R, Ma PC. Facile preparation of melamine foam with superhydrophobic performance and its system integration with prototype equipment for the clean-up of oil spills on water surface. Science of the Total Environment, 2022, 833, 155184Article Link.

 


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